Fig. 3 a) Powder XRD patterns for a powder produced by scraping off and grinding the AACVD sulfur-deficient SnS thin film. 
2θ/°    intensity
10.002	49535
10.0223	49296
10.0426	50229
10.0628	50141
10.0831	49496
10.1033	50424
10.1236	50590
10.1439	50811
10.1641	50780
10.1844	51301
10.2046	51014
10.2249	52082
10.2451	52061
10.2654	51823
10.2857	52033
10.3059	52729
10.3262	52229
10.3464	53271
10.3667	52923
10.3869	53889
10.4072	53614
10.4275	54277
10.4477	54146
10.468	53958
10.4882	54744
10.5085	54687
10.5287	55185
10.549	55675
10.5693	55241
10.5895	55682
10.6098	56324
10.63	56269
10.6503	56566
10.6705	56922
10.6908	57248
10.7111	57381
10.7313	58760
10.7516	57902
10.7718	58343
10.7921	58838
10.8123	58731
10.8326	59148
10.8529	60064
10.8731	59794
10.8934	59941
10.9136	60612
10.9339	60076
10.9541	60827
10.9744	61635
10.9947	61615
11.0149	61904
11.0352	62034
11.0554	62101
11.0757	62921
11.0959	62739
11.1162	63154
11.1365	63326
11.1567	63992
11.177	64570
11.1972	64348
11.2175	65110
11.2377	64803
11.258	65610
11.2783	65961
11.2985	65493
11.3188	66470
11.339	66859
11.3593	66863
11.3795	67497
11.3998	68053
11.4201	68325
11.4403	68043
11.4606	68773
11.4808	69195
11.5011	68954
11.5213	68982
11.5416	69862
11.5619	70311
11.5821	70867
11.6024	70680
11.6226	71525
11.6429	71906
11.6631	71770
11.6834	72578
11.7037	72178
11.7239	73219
11.7442	73514
11.7644	73927
11.7847	73859
11.8049	74194
11.8252	74428
11.8455	74496
11.8657	74813
11.886	75517
11.9062	75923
11.9265	76195
11.9467	76946
11.967	76412
11.9873	77062
12.0075	77652
12.0278	77558
12.048	77606
12.0683	78158
12.0885	78438
12.1088	78953
12.1291	79122
12.1493	79753
12.1696	79940
12.1898	79642
12.2101	79779
12.2303	80684
12.2506	80471
12.2709	81205
12.2911	81555
12.3114	81800
12.3316	82404
12.3519	82240
12.3721	82694
12.3924	82496
12.4127	82937
12.4329	83126
12.4532	83168
12.4734	83227
12.4937	83286
12.5139	83804
12.5342	84059
12.5545	84388
12.5747	84944
12.595	84771
12.6152	85237
12.6355	85263
12.6557	85028
12.676	85847
12.6963	85488
12.7165	85249
12.7368	86487
12.757	86383
12.7773	86577
12.7975	86540
12.8178	86644
12.8381	86433
12.8583	86969
12.8786	86560
12.8988	87225
12.9191	87154
12.9393	87291
12.9596	87276
12.9799	87382
13.0001	87712
13.0204	87505
13.0406	87793
13.0609	87312
13.0811	87662
13.1014	88384
13.1217	87791
13.1419	87747
13.1622	88170
13.1824	88423
13.2027	87554
13.2229	87807
13.2432	88468
13.2635	87490
13.2837	87792
13.304	87927
13.3242	87595
13.3445	88130
13.3647	87969
13.385	87613
13.4053	88497
13.4255	87886
13.4458	88166
13.466	87883
13.4863	87614
13.5066	88290
13.5268	88569
13.5471	87265
13.5673	87874
13.5876	87375
13.6078	87484
13.6281	87064
13.6484	87625
13.6686	87407
13.6889	86782
13.7091	87103
13.7294	86856
13.7496	86336
13.7699	86007
13.7902	86791
13.8104	86590
13.8307	87174
13.8509	86336
13.8712	85975
13.8914	86065
13.9117	85946
13.932	85707
13.9522	85860
13.9725	85842
13.9927	85088
14.013	85452
14.0332	85034
14.0535	84781
14.0738	85201
14.094	85484
14.1143	84446
14.1345	84283
14.1548	85050
14.175	84631
14.1953	84526
14.2156	84267
14.2358	83307
14.2561	83768
14.2763	83688
14.2966	82798
14.3168	82940
14.3371	83745
14.3574	82927
14.3776	83367
14.3979	82936
14.4181	82747
14.4384	82698
14.4586	83216
14.4789	82067
14.4992	82420
14.5194	81795
14.5397	81491
14.5599	82234
14.5802	81818
14.6004	81167
14.6207	80906
14.641	81532
14.6612	80852
14.6815	80623
14.7017	80955
14.722	79814
14.7422	79859
14.7625	79884
14.7828	80015
14.803	79958
14.8233	79711
14.8435	79014
14.8638	78879
14.884	79107
14.9043	78359
14.9246	79128
14.9448	78393
14.9651	78424
14.9853	78088
15.0056	78386
15.0258	77551
15.0461	77847
15.0664	77618
15.0866	77340
15.1069	76669
15.1271	76624
15.1474	76441
15.1676	76778
15.1879	76644
15.2082	76166
15.2284	76550
15.2487	76339
15.2689	75586
15.2892	75219
15.3094	75931
15.3297	75230
15.35	74935
15.3702	74980
15.3905	74721
15.4107	74858
15.431	74597
15.4512	73319
15.4715	74012
15.4918	73946
15.512	73744
15.5323	73680
15.5525	73178
15.5728	73554
15.593	72526
15.6133	72615
15.6336	72097
15.6538	71876
15.6741	72276
15.6943	71240
15.7146	71664
15.7348	71494
15.7551	71704
15.7754	71506
15.7956	71323
15.8159	71190
15.8361	70771
15.8564	70779
15.8766	70479
15.8969	70261
15.9172	70044
15.9374	69770
15.9577	69715
15.9779	69834
15.9982	68971
16.0184	69395
16.0387	69120
16.059	68315
16.0792	68501
16.0995	68371
16.1197	68099
16.14	68508
16.1602	68107
16.1805	67749
16.2008	67252
16.221	67378
16.2413	66493
16.2615	67423
16.2818	66850
16.302	66387
16.3223	66491
16.3426	67002
16.3628	66482
16.3831	66307
16.4033	65725
16.4236	65480
16.4438	65207
16.4641	65585
16.4844	65732
16.5046	65570
16.5249	65320
16.5451	64911
16.5654	64805
16.5856	64461
16.6059	64193
16.6262	63730
16.6464	63648
16.6667	63829
16.6869	63359
16.7072	63037
16.7274	63672
16.7477	63308
16.768	63300
16.7882	62843
16.8085	62203
16.8287	62352
16.849	62517
16.8692	61679
16.8895	62480
16.9098	61971
16.93	61406
16.9503	61287
16.9705	60942
16.9908	61109
17.0111	61140
17.0313	61104
17.0516	60742
17.0718	60761
17.0921	60231
17.1123	60566
17.1326	60356
17.1529	60076
17.1731	60282
17.1934	59746
17.2136	59450
17.2339	59100
17.2541	59438
17.2744	58701
17.2947	58571
17.3149	58746
17.3352	58153
17.3554	58099
17.3757	57975
17.3959	57816
17.4162	57904
17.4365	57914
17.4567	57958
17.477	57911
17.4972	57448
17.5175	56957
17.5377	57131
17.558	56834
17.5783	56584
17.5985	56469
17.6188	56137
17.639	55776
17.6593	55514
17.6795	55709
17.6998	55873
17.7201	55617
17.7403	55514
17.7606	54717
17.7808	54720
17.8011	54957
17.8213	54481
17.8416	54043
17.8619	54540
17.8821	53761
17.9024	54005
17.9226	54404
17.9429	53990
17.9631	53686
17.9834	53266
18.0037	53572
18.0239	53311
18.0442	53312
18.0644	52566
18.0847	52324
18.1049	52178
18.1252	52460
18.1455	52388
18.1657	51968
18.186	51919
18.2062	51674
18.2265	51577
18.2467	51501
18.267	51119
18.2873	51010
18.3075	51088
18.3278	50884
18.348	50667
18.3683	50066
18.3885	50393
18.4088	50042
18.4291	49682
18.4493	49801
18.4696	49497
18.4898	49653
18.5101	49655
18.5303	49807
18.5506	49498
18.5709	48748
18.5911	49124
18.6114	48267
18.6316	48286
18.6519	48891
18.6721	47867
18.6924	48421
18.7127	48025
18.7329	48085
18.7532	47656
18.7734	47539
18.7937	47318
18.8139	47155
18.8342	47713
18.8545	47085
18.8747	46597
18.895	46954
18.9152	46423
18.9355	46125
18.9557	46417
18.976	46521
18.9963	46086
19.0165	46171
19.0368	45803
19.057	45751
19.0773	45619
19.0975	45043
19.1178	45347
19.1381	45072
19.1583	44904
19.1786	44464
19.1988	44667
19.2191	44490
19.2393	44303
19.2596	44387
19.2799	44165
19.3001	44298
19.3204	43641
19.3406	43369
19.3609	44104
19.3811	43827
19.4014	43717
19.4217	43526
19.4419	43135
19.4622	42915
19.4824	42717
19.5027	42348
19.5229	42602
19.5432	42402
19.5635	42258
19.5837	42002
19.604	42173
19.6242	41806
19.6445	42068
19.6647	41636
19.685	41816
19.7053	40982
19.7255	41852
19.7458	41194
19.766	41171
19.7863	40728
19.8065	40673
19.8268	40724
19.8471	40717
19.8673	40067
19.8876	40481
19.9078	40164
19.9281	39874
19.9483	39872
19.9686	40060
19.9889	39497
20.0091	39258
20.0294	39753
20.0496	38866
20.0699	39024
20.0901	39194
20.1104	38933
20.1307	38902
20.1509	38713
20.1712	38852
20.1914	38557
20.2117	38455
20.2319	38221
20.2522	37967
20.2725	38003
20.2927	37856
20.313	37517
20.3332	37714
20.3535	37330
20.3738	37164
20.394	37263
20.4143	36659
20.4345	37148
20.4548	37050
20.475	37173
20.4953	36626
20.5156	36771
20.5358	36386
20.5561	36196
20.5763	36374
20.5966	35916
20.6168	35878
20.6371	35957
20.6574	35449
20.6776	35877
20.6979	35432
20.7181	35336
20.7384	35153
20.7586	35272
20.7789	35433
20.7992	35146
20.8194	34781
20.8397	34882
20.8599	34703
20.8802	34679
20.9004	34496
20.9207	34026
20.941	34620
20.9612	34242
20.9815	34179
21.0017	34224
21.022	33737
21.0422	33837
21.0625	33963
21.0828	33655
21.103	33738
21.1233	33604
21.1435	33247
21.1638	33252
21.184	33544
21.2043	33022
21.2246	33224
21.2448	33161
21.2651	33150
21.2853	33141
21.3056	32665
21.3258	32694
21.3461	32667
21.3664	32656
21.3866	32399
21.4069	32444
21.4271	32177
21.4474	32339
21.4676	32368
21.4879	31938
21.5082	32353
21.5284	32004
21.5487	32086
21.5689	32087
21.5892	31937
21.6094	32034
21.6297	31361
21.65	31768
21.6702	31905
21.6905	31745
21.7107	31437
21.731	31617
21.7512	32238
21.7715	32327
21.7918	32577
21.812	33894
21.8323	35156
21.8525	36795
21.8728	38097
21.893	38924
21.9133	39875
21.9336	39682
21.9538	38672
21.9741	37247
21.9943	36369
22.0146	34979
22.0348	34194
22.0551	33544
22.0754	32802
22.0956	32272
22.1159	31852
22.1361	31565
22.1564	31252
22.1766	31006
22.1969	30617
22.2172	30498
22.2374	30549
22.2577	30043
22.2779	29851
22.2982	29799
22.3184	29716
22.3387	29644
22.359	29226
22.3792	29304
22.3995	29439
22.4197	29484
22.44	29059
22.4602	29243
22.4805	29211
22.5008	28818
22.521	28936
22.5413	28867
22.5615	28681
22.5818	28630
22.602	28272
22.6223	28452
22.6426	28511
22.6628	28176
22.6831	28006
22.7033	28582
22.7236	28521
22.7438	28250
22.7641	28436
22.7844	28179
22.8046	27794
22.8249	28282
22.8451	28002
22.8654	28045
22.8856	28079
22.9059	28048
22.9262	27308
22.9464	27871
22.9667	27815
22.9869	27644
23.0072	27865
23.0274	27882
23.0477	27670
23.068	27772
23.0882	27603
23.1085	27507
23.1287	27597
23.149	27151
23.1692	27461
23.1895	27751
23.2098	27406
23.23	27425
23.2503	27626
23.2705	27195
23.2908	27358
23.311	27336
23.3313	27304
23.3516	27130
23.3718	27509
23.3921	27092
23.4123	27702
23.4326	27485
23.4528	27015
23.4731	27195
23.4934	27190
23.5136	26995
23.5339	27098
23.5541	27177
23.5744	27028
23.5946	26816
23.6149	27057
23.6352	26740
23.6554	27100
23.6757	26972
23.6959	26875
23.7162	26592
23.7364	26596
23.7567	26747
23.777	26937
23.7972	26767
23.8175	26806
23.8377	26468
23.858	26577
23.8783	26573
23.8985	26583
23.9188	26617
23.939	26456
23.9593	26282
23.9795	26279
23.9998	26644
24.0201	26526
24.0403	26328
24.0606	26439
24.0808	26261
24.1011	26185
24.1213	26340
24.1416	26133
24.1619	26472
24.1821	26661
24.2024	26544
24.2226	26583
24.2429	26450
24.2631	26331
24.2834	26609
24.3037	26660
24.3239	26304
24.3442	26564
24.3644	26249
24.3847	26131
24.4049	26248
24.4252	26421
24.4455	26206
24.4657	26579
24.486	26444
24.5062	26436
24.5265	26234
24.5467	26364
24.567	26356
24.5873	26543
24.6075	26498
24.6278	26435
24.648	26615
24.6683	26345
24.6885	26546
24.7088	26437
24.7291	26475
24.7493	26826
24.7696	26389
24.7898	26447
24.8101	26678
24.8303	26599
24.8506	26627
24.8709	26346
24.8911	26950
24.9114	26586
24.9316	26313
24.9519	26517
24.9721	26454
24.9924	26888
25.0127	26567
25.0329	26648
25.0532	26596
25.0734	27001
25.0937	26891
25.1139	26767
25.1342	26700
25.1545	27196
25.1747	27090
25.195	27040
25.2152	26901
25.2355	26929
25.2557	26912
25.276	27291
25.2963	26928
25.3165	26966
25.3368	27139
25.357	27466
25.3773	27303
25.3975	27471
25.4178	27545
25.4381	27480
25.4583	27521
25.4786	27357
25.4988	27336
25.5191	27561
25.5393	27696
25.5596	27711
25.5799	28004
25.6001	27656
25.6204	28118
25.6406	28192
25.6609	27892
25.6811	28350
25.7014	28539
25.7217	29090
25.7419	29374
25.7622	29988
25.7824	30840
25.8027	32320
25.8229	34485
25.8432	37181
25.8635	41184
25.8837	44538
25.904	46327
25.9242	46852
25.9445	46515
25.9647	45304
25.985	42930
26.0053	40317
26.0255	38517
26.0458	36354
26.066	34618
26.0863	32905
26.1065	32265
26.1268	31538
26.1471	30943
26.1673	30438
26.1876	30116
26.2078	30103
26.2281	29724
26.2483	29585
26.2686	29495
26.2889	28930
26.3091	29280
26.3294	29292
26.3496	28973
26.3699	29085
26.3901	29142
26.4104	29163
26.4307	29204
26.4509	29003
26.4712	29043
26.4914	29431
26.5117	29226
26.5319	29289
26.5522	29318
26.5725	29446
26.5927	29030
26.613	29446
26.6332	29387
26.6535	29624
26.6737	29315
26.694	29801
26.7143	29582
26.7345	29913
26.7548	29805
26.775	29788
26.7953	29891
26.8155	30033
26.8358	30178
26.8561	30678
26.8763	30344
26.8966	30823
26.9168	30872
26.9371	30654
26.9573	30866
26.9776	30775
26.9979	31111
27.0181	31549
27.0384	31862
27.0586	32154
27.0789	32218
27.0991	33008
27.1194	33106
27.1397	33877
27.1599	34929
27.1802	36386
27.2004	37803
27.2207	40509
27.241	43462
27.2612	47906
27.2815	52990
27.3017	57360
27.322	59227
27.3422	57356
27.3625	53838
27.3828	51119
27.403	47040
27.4233	42607
27.4435	39306
27.4638	36590
27.484	35590
27.5043	34079
27.5246	33276
27.5448	32871
27.5651	32652
27.5853	32183
27.6056	32230
27.6258	32123
27.6461	31957
27.6664	32063
27.6866	31720
27.7069	31964
27.7271	31911
27.7474	31708
27.7676	31434
27.7879	31780
27.8082	32115
27.8284	32023
27.8487	32021
27.8689	31647
27.8892	31752
27.9094	31899
27.9297	31989
27.95	32173
27.9702	32222
27.9905	32169
28.0107	31823
28.031	32215
28.0512	32393
28.0715	32199
28.0918	32125
28.112	32068
28.1323	32043
28.1525	32031
28.1728	32255
28.193	32208
28.2133	32474
28.2336	32460
28.2538	32329
28.2741	32155
28.2943	32564
28.3146	32477
28.3348	32634
28.3551	32610
28.3754	32471
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